Strength of a Weak Bond Connecting Flexible Polymer Chains
نویسندگان
چکیده
منابع مشابه
Modeling polymer grafted nanoparticle networks reinforced by high-strength chains.
Using a multi-scale computational approach, we determine the effect of introducing a small fraction of high-strength connections between cross-linked nanoparticles. The nanoparticles' rigid cores are decorated with a corona of grafted polymers, which contain reactive functional groups at the chain ends. With the overlap of neighboring coronas, these reactive groups can form weak labile bonds, w...
متن کاملTransitions of tethered polymer chains: a simulation study with the bond fluctuation lattice model.
A polymer chain tethered to a surface may be compact or extended, adsorbed or desorbed, depending on interactions with the surface and the surrounding solvent. This leads to a rich phase diagram with a variety of transitions. To investigate these transitions we have performed Monte Carlo simulations of a bond fluctuation model with Wang-Landau and umbrella sampling algorithms in a two-dimension...
متن کاملGluing nanoparticles with a polymer bonding layer: the strength of an adhesive bond.
The adhesive joint between silica nanoparticles and ultrathin poly(vinylpyridine) (PVP) layers (thickness between 3 and 100 nm) was tested using the cantilever of an atomic force microscope. Specifically, the strength of the adhesive bond (or practical adhesion) was probed in a tearing contact mode, when the particle was removed by applying a tangential force parallel to the substrate surface. ...
متن کاملConformation of a flexible polymer in explicit solvent: Accurate solvation potentials for Lennard-Jones chains.
The conformation of a polymer chain in solution is coupled to the local structure of the surrounding solvent and can undergo large changes in response to variations in solvent density and temperature. The many-body effects of solvent on the structure of an n-mer polymer chain can be formally mapped to an exact n-body solvation potential. Here, we use a pair decomposition of this n-body potentia...
متن کاملLaboratory evaluation of shear bond strength of porcelain repair methods
Introduction: Porcelain fracture is a relatively common problem in clinical dental practice. Various methods have been proposed for repairing porcelain fractures including direct composite resin repair or construction of a porcelain laminate veneer and its cementation with a resin cement. Evaluation of shear bond strength of porcelain repair methods was the purpose of this study. Methods: Tw...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Biophysical Journal
سال: 1999
ISSN: 0006-3495
DOI: 10.1016/s0006-3495(99)77399-6